Hydrogen Engine

Some have theorized that in the future hydrogen might replace such fuels. Furthermore, with the introduction of hydrogen fuel cell technology, the use of internal combustion engines may be phased out. The advantage of hydrogen is that its combustion produces only water. This is unlike the combustion of fossil fuels, which produce carbon dioxide, a known green house gas GHG, carbon monoxide resulting from incomplete combustion, and other local and atmospheric pollutants such as sulfur dioxide and nitrogen oxides that lead to urban respiratory problems, acid rain, and ozone gas problems. However, free hydrogen for fuel does not occur naturally, burning it liberates less energy than it takes to produce hydrogen in the first place due to the second law of thermodynamics.
Although there are multiple ways of producing free hydrogen, those require converting combustible molecules into hydrogen, so hydrogen does not solve any energy crisis, moreover, it only addresses the issue of portability and some pollution issues. The disadvantage of hydrogen in many situations is its storage. Liquid hydrogen has extremely low density- 14 times lower than water and requires extensive insulation, whilst gaseous hydrogen requires heavy tankage. Although hydrogen has a higher specific energy, the volumetric energetic storage is still roughly five times lower than petrol, even when liquified. (The 'Hydrogen on Demand' process, designed by Steven Amendola, creates hydrogen as it is needed, but has other issues, such as the high price of the sodium borohydride, the raw material. Sodium borohydride is renewable and could become cheaper if more widely produced.)

Engine-Efficiency

The efficiency of various types of internal combustion engines vary. Most gasoline fueled internal combustion engines, even when aided with turbochargers and stock efficiency aids, have a mechanical efficiency of about 20% . The efficiency may be as high as 37% at the optimum operating point in engines where this is a high priority such as that of the Prius. Most internal combustion engines waste about 36% of the energy in gasoline as heat lost to the cooling system and another 38% through the exhaust. The rest, about 6%, is lost to friction. But this technology is one of the leading factors to global warming and pollution.
Hydrogen Fuel Injection, or HFI, is an engine add on system that improves the fuel economy of internal combustion engines by injecting hydrogen as a combustion enhancement into the intake manifold. Fuel economy gains of 15% to 50% can be seen[citation needed]. A small amount of hydrogen added to the intake air-fuel charge increases the octane rating of the combined fuel charge and enhances the flame velocity, thus permitting the engine to operate with more advanced ignition timing, a higher compression ratio, and a leaner air-to-fuel mixture than otherwise possible. The result is lower pollution with more power and increased efficiency. Some HFI systems use an on board electrolyzer to generate the hydrogen used but this appears to have little credibility at this time given the small amounts of gas produced from them. A small tank of pressurized hydrogen can also be used, but this method necessitates refilling and Hydrogen in liquid form is difficult to store in any usable volume.
There has also been discussion of new types of internal combustion engines, such as the Scuderi Split Cycle Engine, that utilize high compression pressures in excess of 2000 psi and combust after top-dead-center (the highest & most compressed point in an internal combustion piston stroke). The claimed efficiency of this engine, by calculation, is 42%. This has yet to be demonstrated as of March 2007.

engine

The internal combustion engine is an engine in which the combustion, or rapid oxidation, of gas and air occurs in a confined space called a combustion chamber. This exothermic reaction of a fuel with an oxidizer creates gases of high temperature and pressure, which are permitted to expand. The defining feature of an internal combustion engine is that useful work is performed by the expanding hot gases acting directly to cause pressure, further causing movement of the piston inside the cylinder. For example by acting on pistons, rotors, or even by pressing on and moving the entire engine itself.
This contrasts with external combustion engines, such as steam engines and Stirling engines, which use an external combustion chamber to heat a separate working fluid, which then in turn does work, for example by moving a piston.
The term Internal Combustion Engine (ICE) is almost always used to refer specifically to reciprocating engines, Wankel engines and similar designs in which combustion is intermittent. However, continuous combustion engines, such as jet engines, most rockets and many gas turbines are also internal combustion engines.